Source:http://linkedlifedata.com/resource/pubmed/id/15750228
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
Pt 3
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| pubmed:dateCreated |
2005-3-7
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| pubmed:abstractText |
In the title complex, [Mn(C5H4NO)2(C5H5NO)2]n or [Mn(mu-3-PyO)2(3-PyOH)2]n (3-PyO- is the pyridin-3-olate anion and 3-PyOH is pyridin-3-ol), the Mn(II) atom lies on an inversion centre and has octahedral geometry, defined by two N atoms and two deprotonated exocyclic O atoms of symmetry-related pyridin-3-olate ligands [Mn-N = 2.3559 (14) A and Mn-O = 2.1703 (11) A], as well as two N atoms of terminal 3-PyOH ligands [Mn-N = 2.3482 (13) A]. The Mn(II) atoms are bridged by the deprotonated pyridin-3-olate anion into a layer structure, generating sheets in the (-101) plane. These sheets are linked by O-H...O hydrogen bonds. There are also pi-pi and C-H...pi interactions in the crystal structure.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Mar
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| pubmed:issn |
0108-2701
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| pubmed:author | |
| pubmed:issnType |
Print
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| pubmed:volume |
61
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| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
m133-5
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| pubmed:year |
2005
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| pubmed:articleTitle |
Poly[[bis(pyridin-3-ol)manganese(II)]-di-mu-pyridin-3-olato].
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| pubmed:affiliation |
School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, People's Republic of China. shangao67@yahoo.com
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| pubmed:publicationType |
Journal Article
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