Linked Life Data

15739390

Source:http://linkedlifedata.com/resource/pubmed/id/15739390

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
2
pubmed:dateCreated
2005-3-2
pubmed:abstractText
The stability constant of metal complexes is an important chemical parameter. There are many methods for its determination, but few analyst has calculated it with high performance liquid chromatography (HPLC). In the present paper a new model for determining the stability constant of metal complexes with on-column derivatization reversed phase HPLC has been proposed where complexation forming reactions are taking place in the mobile phase. Based on the retention mechanism of neutral complexes, the equation for calculation is deduced. It has been applied to some cations (Hg2+, Pb2+, Ni2+, Cu2+, Ag+, Hg+)-DDTC complexes. The results are in agreement with those given in the literature. Then, a simple, practical and rapid graphic method is studied for monovalent metal complexes. The stability constants can be obtained simply as the quotient of the line slope and the axis intercept of the linear dependence. The relations derived in this paper may be used not only for calculating the stability constants from chromatographic measurements but also for optimizing the process of separation based on the values of the stability constants available in literature.
pubmed:language
chi
pubmed:journal
pubmed:citationSubset
IM
pubmed:status
MEDLINE
pubmed:month
Mar
pubmed:issn
1000-8713
pubmed:author
pubmed:issnType
Print
pubmed:volume
15
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
99-101
pubmed:meshHeading
pubmed:year
1997
pubmed:articleTitle
[Determination of stability constants of metal complexes by on-column derivatization reversed phase high performance liquid chromatography].
pubmed:affiliation
Research Center of Physical and Chemical Analysis, Hebei University, Baoding, 071002.
pubmed:publicationType
Journal Article, English Abstract, Research Support, Non-U.S. Gov't