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PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
26 Pt 1
pubmed:dateCreated
2005-2-8
pubmed:abstractText
In single-molecule transistors, we observe inelastic cotunneling features that correspond energetically to vibrational excitations of the molecule, as determined by Raman and infrared spectroscopy. This is a form of inelastic electron tunneling spectroscopy of single molecules, with the transistor geometry allowing in situ tuning of the electronic states via a gate electrode. The vibrational features shift and change shape as the electronic levels are tuned near resonance, indicating significant modification of the vibrational states. When the molecule contains an unpaired electron, we also observe vibrational satellite features around the Kondo resonance.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Dec
pubmed:issn
0031-9007
pubmed:author
pubmed:issnType
Print
pubmed:day
31
pubmed:volume
93
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
266802
pubmed:year
2004
pubmed:articleTitle
Inelastic electron tunneling via molecular vibrations in single-molecule transistors.
pubmed:affiliation
Department of Physics and Astronomy, Rice University, 6100 Main Street, Houston, Texas 77005, USA.
pubmed:publicationType
Journal Article