15646992

Source:http://linkedlifedata.com/resource/pubmed/id/15646992

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0220781, umls-concept:C0439810, umls-concept:C0449445, umls-concept:C1698941, umls-concept:C1883254
pubmed:issue	2
pubmed:dateCreated	2005-1-13
pubmed:abstractText	[Reaction: see text] A total synthesis of (+/-)-mycothiazole and a formal enantioselective approach have been achieved from 2,4-dibromothiazole. A chain extension of a homoallylic alcohol proceeding through an unsaturated sultone intermediate, generated by ring-closing metathesis, was used as a key step for the elaboration of the conjugated (Z)-dienol moiety.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/100890393
pubmed:citationSubset	IM
pubmed:chemical	http://linkedlifedata.com/resource/pubmed/chemical/Antineoplastic Agents, http://linkedlifedata.com/resource/pubmed/chemical/Thiazoles
pubmed:status	MEDLINE
pubmed:month	Jan
pubmed:issn	1523-7060
pubmed:author	pubmed-author:CossyJanineJ, pubmed-author:Le FlohicAlexandreA, pubmed-author:MeyerChristopheC
pubmed:issnType	Print
pubmed:day	20
pubmed:volume	7
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	339-42
pubmed:dateRevised	2006-11-15
pubmed:meshHeading	pubmed-meshheading:15646992-Antineoplastic Agents, pubmed-meshheading:15646992-Molecular Structure, pubmed-meshheading:15646992-Stereoisomerism, pubmed-meshheading:15646992-Thiazoles
pubmed:year	2005
pubmed:articleTitle	Total synthesis of (+/-)-mycothiazole and formal enantioselective approach.
pubmed:affiliation	Laboratoire de Chimie Organique, associé au CNRS, ESPCI, 10 rue Vauquelin, 75231 Paris 05, France.
pubmed:publicationType	Journal Article, Research Support, Non-U.S. Gov't