Source:http://linkedlifedata.com/resource/pubmed/id/15606166
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
26
|
| pubmed:dateCreated |
2004-12-20
|
| pubmed:abstractText |
Sequential reaction of two different hemilabile ligands (Ph(2)PCH(2)CH(2)X)(2)Ar (X = S, Ar = C(6)H(4) or C(6)(CH(3))(4); X = NCH(3), Ar = C(6)H(4); X = O, Ar = 9,10-C(14)H(8)) with a Rh(I) metal center resulted in the formation of heteroligated metallomacrocycles in high yield. The specific reaction conditions for each pair of hemilabile ligands are discussed. The solid-state structure of [[1,4-(Ph(2)PCH(2)CH(2)S)(2)C(6)H(4)]-[1,4-(Ph(2)PCH(2)CH(2)S)(2)C(6)(CH(3))(4)]Rh(2)](BF(4))(2), as determined by X-ray crystallography, is presented.
|
| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Dec
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| pubmed:issn |
0020-1669
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| pubmed:author | |
| pubmed:issnType |
Print
|
| pubmed:day |
27
|
| pubmed:volume |
43
|
| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
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| pubmed:pagination |
8233-5
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| pubmed:year |
2004
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| pubmed:articleTitle |
Heteroligated metallomacrocycles generated via the weak-link approach.
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| pubmed:affiliation |
Department of Chemistry and Institute for Nanotechnology, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208-3113, USA.
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| pubmed:publicationType |
Journal Article
|