Source:http://linkedlifedata.com/resource/pubmed/id/15606091
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Predicate | Object |
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
26
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pubmed:dateCreated |
2004-12-20
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pubmed:abstractText |
[reaction: see text] A fluorine-labeled selenide linker for installing terminal isolated olefins has been synthesized in high overall yield. The resin-bound linker could be glycosylated both with glycosyl trichloroacetimidates and glycosyl fluorides. The linker did not decompose after oxidation with tBuOOH but underwent beta-elimination when it was subjected to heat. This allowed the released n-pentenyl glycoside 15 to be isolated in excellent yield and purity after filtration.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:citationSubset |
IM
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pubmed:chemical | |
pubmed:status |
MEDLINE
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pubmed:month |
Dec
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pubmed:issn |
1523-7060
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pubmed:author | |
pubmed:issnType |
Print
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pubmed:day |
23
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pubmed:volume |
6
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
4885-8
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pubmed:dateRevised |
2006-11-15
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pubmed:meshHeading |
pubmed-meshheading:15606091-Glucosides,
pubmed-meshheading:15606091-Glycosylation,
pubmed-meshheading:15606091-Hydrocarbons, Fluorinated,
pubmed-meshheading:15606091-Magnetic Resonance Spectroscopy,
pubmed-meshheading:15606091-Molecular Structure,
pubmed-meshheading:15606091-Oxidation-Reduction,
pubmed-meshheading:15606091-Selenium Compounds
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pubmed:year |
2004
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pubmed:articleTitle |
A fluorinated selenide linker for solid-phase synthesis of n-pentenyl glycosides.
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pubmed:affiliation |
Organic Chemistry, Department of Chemistry, Umeå University, SE-901 87 Umeå, Sweden.
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pubmed:publicationType |
Journal Article,
Research Support, Non-U.S. Gov't
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