Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
3-4
pubmed:dateCreated
2004-11-15
pubmed:abstractText
Cobalt(II) meso-tetraphenylporphyrin (CoTPP)/acrylate hybrid thin films were prepared by CoTPP sublimation and reactive monomer evaporation onto the glass substrate in vacuum conditions. Deposited CoTPP/acrylate thin films were in situ photopolymerized. The oxygen-uptake behaviors of CoTPP/acrylate films were investigated by means of sorption measurements, monitored by gravimetric means, and analyzed using dual mode sorption model. The loading percent of CoTPP in the film was adjusted up to 60% by controlling the CoTPP sublimation rate. The thickness of the CoTPP/acrylate hybrid film was about 200 nm and oxygen-uptake data obtained from the sorption measurements indicated that CoTPP molecules in the CoTPP/acrylate hybrid films were able to bind oxygen molecules reversibly.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Nov
pubmed:issn
0927-7765
pubmed:author
pubmed:issnType
Print
pubmed:day
15
pubmed:volume
38
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
161-5
pubmed:dateRevised
2009-10-16
pubmed:meshHeading
pubmed:year
2004
pubmed:articleTitle
Dispersion of functional tetraphenylporphyrin-ligated metal into ultra-thin flexible acrylate films. 2. Oxygen-uptake properties.
pubmed:affiliation
Department of Chemical Engineering, Pusan National University, Jangjeon-dong, Gumjeong-gu, Busan 609-735, South Korea. choe@pusan.ac.kr
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't