15514761

Source:http://linkedlifedata.com/resource/pubmed/id/15514761

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0035493, umls-concept:C0439851, umls-concept:C0443286, umls-concept:C1552596, umls-concept:C1947931
pubmed:issue	17
pubmed:dateCreated	2004-10-29
pubmed:abstractText	A series of carbene complexes RhCl(CR'2)(PR3)2(R=Ph, Tol, Me, R'= Ph and Tol) have been synthesised through direct reaction of photochemically generated free diarylcarbene with RhCl(CO)(PR3)2. This route to carbene complexes demonstrates the reactivity of simple diarylcarbenes towards transition metal complexes. The reactivity of some of these complexes towards H2, C2H4 and Et3SiH has been investigated.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/101176026
pubmed:status	PubMed-not-MEDLINE
pubmed:month	Sep
pubmed:issn	1477-9226
pubmed:author	pubmed-author:DuckettSimon BSB, pubmed-author:Galvez-LopezMaria-DoloresMD, pubmed-author:PerutzRobin NRN, pubmed-author:SchottDanieleD
pubmed:issnType	Print
pubmed:day	7
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	2746-9
pubmed:year	2004
pubmed:articleTitle	Direct reaction of photogenerated diarylcarbenes at square-planar rhodium(I).
pubmed:affiliation	Department of Chemistry, University of York, York, UK.
pubmed:publicationType	Journal Article