Source:http://linkedlifedata.com/resource/pubmed/id/15510280
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
21
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pubmed:dateCreated |
2004-10-28
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pubmed:abstractText |
The synthesis of the new polynucleating ligand 1,3-bis-(3-oxo-3-(2-hydroxyphenyl)-propionyl)-benzene (H4L) is reported along with the preparation, structure and properties of its dinuclear complexes [Cu(2)(H(2)L)(2)(py)(2)](1), [Ni(2)(H(2)L)(2)(py)(4)](2), [Mn(2)(H(2)L)(2)(dmf)(4)](3), [Co(2)(H(2)L)(2)(dmf)(4)](4) and [Co(2)(H(2)L)(2)(MeOH)(4)](5), respectively. In complexes 1 to 5, the polydentate ligand is in its bis-deprotonated form, chelating the metals through its [small beta]-diketonate moieties. Magnetic measurements show that the metals within these molecules are maintained almost mutually independent.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:status |
PubMed-not-MEDLINE
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pubmed:month |
Nov
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pubmed:issn |
1477-9226
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pubmed:author | |
pubmed:issnType |
Print
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pubmed:day |
7
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
3586-92
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pubmed:year |
2004
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pubmed:articleTitle |
Complexes of a novel multinucleating poly-beta-diketonate ligand.
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pubmed:affiliation |
Departament de Química Inorgànica, Universitat de Barcelona, Diagonal 647, 08028 Barcelona, Spain. guillem.aromi@qi.ub.es.
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pubmed:publicationType |
Journal Article
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