Source:http://linkedlifedata.com/resource/pubmed/id/15493919
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Predicate | Object |
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
42
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pubmed:dateCreated |
2004-10-20
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pubmed:abstractText |
An analysis of torsional motions about glycosidic bonds in a disaccharide is undertaken using residual dipolar coupling measurements and selective immobilization of the reducing end sugar to provide a suitable motional reference. The immobilization is accomplished by using the short chain of an alkyl glycoside to anchor the disaccharide to a bilayer medium aligned in magnetic field. Motions about the beta-(1-4) linkage of the n-butyl-4-O-beta-d-galactopyranosyl-alpha-d-mannopyranoside are shown to be substantial (+/-40 degrees ) and in good agreement with predictions of a fully solvated molecular dynamics simulation.
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pubmed:grant | |
pubmed:language |
eng
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pubmed:journal | |
pubmed:citationSubset |
IM
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pubmed:chemical | |
pubmed:status |
MEDLINE
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pubmed:month |
Oct
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pubmed:issn |
0002-7863
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pubmed:author | |
pubmed:issnType |
Print
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pubmed:day |
27
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pubmed:volume |
126
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
13636-8
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pubmed:dateRevised |
2008-1-17
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pubmed:meshHeading |
pubmed-meshheading:15493919-Carbohydrate Conformation,
pubmed-meshheading:15493919-Disaccharides,
pubmed-meshheading:15493919-Galactose,
pubmed-meshheading:15493919-Glycosides,
pubmed-meshheading:15493919-Mannose,
pubmed-meshheading:15493919-Models, Molecular,
pubmed-meshheading:15493919-Thermodynamics
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pubmed:year |
2004
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pubmed:articleTitle |
Glycosidic torsional motions in a bicelle-associated disaccharide from residual dipolar couplings.
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pubmed:affiliation |
Complex Carbohydrate Research Center, University of Georgia, Athens, Georgia 30602, USA.
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pubmed:publicationType |
Journal Article,
Research Support, U.S. Gov't, P.H.S.
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