Linked Life Data

15477156

Source:http://linkedlifedata.com/resource/pubmed/id/15477156

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
13
pubmed:dateCreated
2004-10-12
pubmed:abstractText
Effects of pressure and solvents on the infrared spectrum of phenol in solutions have been investigated using a hydrostatic high-pressure cell with synthetic diamond windows. For the first time, we performed a quantitative investigation of the effect of pressure on the absolute intensity of O-H stretching mode up to 150 MPa (in CCl4) and 200 MPa (in CS2). For comparison, we measured the effect of solvents on the absorption intensity. The Polo-Wilson theory, which is the most traditional theory for medium effects on the intensity, was tested for present results. The pressure dependence was in sufficient agreement with their formula, while the solvent dependence is unsatisfactory. This suggests that the traditional intensity correction by Polo-Wilson's formula is practically valid for pressure-tuning infrared experiments.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Nov
pubmed:issn
1386-1425
pubmed:author
pubmed:issnType
Print
pubmed:volume
60
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
3135-9
pubmed:meshHeading
pubmed:year
2004
pubmed:articleTitle
Effects of pressure and solvents on the infrared absorption intensity of the O-H stretching mode of phenol in solutions.
pubmed:affiliation
Department of Applied Chemistry, College of Science and Engineering, Ritsumeikan University, 1-1-1, Noji-higashi, Kusatsu, Shiga 525-8577, Japan.
pubmed:publicationType
Journal Article