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pubmed-article:15453740rdf:typepubmed:Citationlld:pubmed
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pubmed-article:15453740pubmed:issue39lld:pubmed
pubmed-article:15453740pubmed:dateCreated2004-9-29lld:pubmed
pubmed-article:15453740pubmed:abstractTextAcrolein dimethyl acetal (ADMA) can be copolymerized with ethene using a cationic alpha-diimine palladium chelate catalyst to yield branched copolymers. Catalyst deactivation occurs via methanol elimination to give an inert eta3-1-methoxyallyl palladium species. This process can be retarded by the addition of an aliquot of methanol to the reaction mixture, increasing overall catalyst productivity.lld:pubmed
pubmed-article:15453740pubmed:languageenglld:pubmed
pubmed-article:15453740pubmed:journalhttp://linkedlifedata.com/r...lld:pubmed
pubmed-article:15453740pubmed:statusPubMed-not-MEDLINElld:pubmed
pubmed-article:15453740pubmed:monthOctlld:pubmed
pubmed-article:15453740pubmed:issn0002-7863lld:pubmed
pubmed-article:15453740pubmed:authorpubmed-author:LiWeidongWlld:pubmed
pubmed-article:15453740pubmed:authorpubmed-author:MeetsmaAukeAlld:pubmed
pubmed-article:15453740pubmed:authorpubmed-author:HessenBartBlld:pubmed
pubmed-article:15453740pubmed:authorpubmed-author:ZhangXiaochun...lld:pubmed
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pubmed-article:15453740pubmed:day6lld:pubmed
pubmed-article:15453740pubmed:volume126lld:pubmed
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pubmed-article:15453740pubmed:authorsCompleteYlld:pubmed
pubmed-article:15453740pubmed:pagination12246-7lld:pubmed
pubmed-article:15453740pubmed:dateRevised2008-1-17lld:pubmed
pubmed-article:15453740pubmed:year2004lld:pubmed
pubmed-article:15453740pubmed:articleTitlePalladium-catalyzed copolymerization of ethene with acrolein dimethyl acetal: catalyst action and deactivation.lld:pubmed
pubmed-article:15453740pubmed:affiliationDutch Polymer Institute/Center for Catalytic Olefin Polymerization, Stratingh Institute for Chemistry and Chemical Engineering, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands.lld:pubmed
pubmed-article:15453740pubmed:publicationTypeJournal Articlelld:pubmed