Linked Life Data

15453740

Source:http://linkedlifedata.com/resource/pubmed/id/15453740

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
39
pubmed:dateCreated
2004-9-29
pubmed:abstractText
Acrolein dimethyl acetal (ADMA) can be copolymerized with ethene using a cationic alpha-diimine palladium chelate catalyst to yield branched copolymers. Catalyst deactivation occurs via methanol elimination to give an inert eta3-1-methoxyallyl palladium species. This process can be retarded by the addition of an aliquot of methanol to the reaction mixture, increasing overall catalyst productivity.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Oct
pubmed:issn
0002-7863
pubmed:author
pubmed:issnType
Print
pubmed:day
6
pubmed:volume
126
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
12246-7
pubmed:dateRevised
2008-1-17
pubmed:year
2004
pubmed:articleTitle
Palladium-catalyzed copolymerization of ethene with acrolein dimethyl acetal: catalyst action and deactivation.
pubmed:affiliation
Dutch Polymer Institute/Center for Catalytic Olefin Polymerization, Stratingh Institute for Chemistry and Chemical Engineering, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands.
pubmed:publicationType
Journal Article