Linked Life Data

15341842

Source:http://linkedlifedata.com/resource/pubmed/id/15341842

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
2
pubmed:dateCreated
2004-9-2
pubmed:abstractText
The semi-batch precipitation process of silica from sodium silicate and sulphuric acid has been structured into a primary particle production stage, an aggregation process until the gel point is reached and finally a gel fragmentation and compaction process. The progress of aggregation was analyzed by photon correlation spectroscopy. The reaction limited aggregation kernel was found to be proportional to B'(t)(q(p - q))A/2, where A assumes the value of one. The quantity B'(t) varies between 3.4 x 10(-20) and 2.6 x 10(-20) 1/min and is only a weak function of time. The stability ratio W for the aggregation process decreases with increasing aggregate size. During the period after the gel point the gel fragmentates. The gel clusters have an initial fractal dimension of approximately 1.8 which rapidly increases to 2.4 and stays roughly constant until the end of the process. The specific surface area decreases from 480 to 300 m2/g. The primary particles have a uniform size of 22.7 nm.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Sep
pubmed:issn
0021-9797
pubmed:author
pubmed:issnType
Print
pubmed:day
15
pubmed:volume
277
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
316-26
pubmed:dateRevised
2009-11-11
pubmed:meshHeading
pubmed:year
2004
pubmed:articleTitle
Investigations on the semi-batch precipitation of silica.
pubmed:affiliation
Institut für Thermische Verfahrenstechnik, University of Karlsruhe (TH), 76128 Karlsruhe, Germany. jan.schlomach@ciw.uni-karlsruhe.de
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't