Source:http://linkedlifedata.com/resource/pubmed/id/15303861
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
32
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| pubmed:dateCreated |
2004-8-12
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| pubmed:abstractText |
A cyclopentadienyl radical annelated with two homoadamantene frameworks 1 was synthesized and isolated in stable, crystalline form by the single-electron oxidation of the corresponding cyclopentadienyl anion. The X-ray structure clearly demonstrated distinct bond alternation in the cyclopentadienyl ring, suggesting that radical 1 has the characteristics of a spin-localized 2,4-cyclopentadien-1-yl radical. The two homoadamantene frameworks are nonequivalent in crystals at 100 K, while ESR spectra indicated that they are equivalent in toluene at room temperature due to rapid changes in conformation.
|
| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Aug
|
| pubmed:issn |
0002-7863
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| pubmed:author | |
| pubmed:issnType |
Print
|
| pubmed:day |
18
|
| pubmed:volume |
126
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| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
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| pubmed:pagination |
9930-1
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| pubmed:dateRevised |
2008-1-17
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| pubmed:year |
2004
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| pubmed:articleTitle |
Spin-localized cyclopentadienyl radical annelated with homoadamantene frameworks: isolation, X-ray crystal structure, and ESR characterization.
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| pubmed:affiliation |
Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan. kitagawa@scl.kyoto-u.ac.jp
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| pubmed:publicationType |
Journal Article
|