Source:http://linkedlifedata.com/resource/pubmed/id/15291526
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Predicate | Object |
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
31
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pubmed:dateCreated |
2004-8-4
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pubmed:abstractText |
The vibrational circular dichroism (VCD) technique was applied to carbohydrates and produced a glycoside characteristic VCD band, which was named the "glycoside band." It confirmed that this vibration was related to anomeric configurations of carbohydrates in the case of the d-series by means of isotope substitution. This band is defined as a negative, sharp, and intense VCD band at around 1145 cm-1, exhibited by d-sugars with an axial alpha-glycosidic linkage in the 4C1 conformation. As applications of this band, the VCD studies of the maltose-cellobiose mixture and the monitoring of the amyloglucosidase reaction were examined.
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pubmed:commentsCorrections | |
pubmed:language |
eng
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pubmed:journal | |
pubmed:citationSubset |
IM
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pubmed:chemical |
http://linkedlifedata.com/resource/pubmed/chemical/Cellobiose,
http://linkedlifedata.com/resource/pubmed/chemical/Disaccharides,
http://linkedlifedata.com/resource/pubmed/chemical/Glucose,
http://linkedlifedata.com/resource/pubmed/chemical/Glycosides,
http://linkedlifedata.com/resource/pubmed/chemical/Maltose
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pubmed:status |
MEDLINE
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pubmed:month |
Aug
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pubmed:issn |
0002-7863
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pubmed:author | |
pubmed:issnType |
Print
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pubmed:day |
11
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pubmed:volume |
126
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
9496-7
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pubmed:dateRevised |
2008-1-17
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pubmed:meshHeading |
pubmed-meshheading:15291526-Carbohydrate Conformation,
pubmed-meshheading:15291526-Cellobiose,
pubmed-meshheading:15291526-Circular Dichroism,
pubmed-meshheading:15291526-Disaccharides,
pubmed-meshheading:15291526-Glucose,
pubmed-meshheading:15291526-Glycosides,
pubmed-meshheading:15291526-Maltose,
pubmed-meshheading:15291526-Spectrophotometry, Infrared
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pubmed:year |
2004
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pubmed:articleTitle |
Specific band observed in VCD predicts the anomeric configuration of carbohydrates.
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pubmed:affiliation |
Division of Biological Sciences, Graduate School of Science, Frontier Research Center for Post-Genomic Science and Technology, Hokkaido University, Kita-ku, Sapporo 001-0021, Japan. kmonde@glyco.sci.hokudai.ac.jp
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pubmed:publicationType |
Journal Article,
Research Support, Non-U.S. Gov't
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