Linked Life Data

15281825

Source:http://linkedlifedata.com/resource/pubmed/id/15281825

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
30
pubmed:dateCreated
2004-7-29
pubmed:abstractText
Chiral, facial tris-cyclometalated Ir(III) complexes, fac-Delta-Ir(pppy)(3), fac-Lambda-Ir(pppy)(3), fac-Lambda-IrL (where pppy is (8R,10R)-2-(2'-phenyl)-4,5-pinenopyridine and L is a tripodal ligand comprising three pppy moieties connected through a mesityl spacer) have been synthesized and characterized. In IrL, NMR and CD studies indicate that only one diastereomer is formed, with the Lambda configuration at the metal center, whereas enantiopure pppy yields the fac-Lambda- and the fac-Delta-stereoisomer in a ratio 2:3. fac-Lambda-IrL was structurally characterized using X-ray crystallography. The luminescence properties including CPL, of the three complexes and their sensitivity to dioxygen were examined.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Aug
pubmed:issn
0002-7863
pubmed:author
pubmed:issnType
Print
pubmed:day
4
pubmed:volume
126
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
9339-48
pubmed:year
2004
pubmed:articleTitle
Diastereoselective formation of chiral tris-cyclometalated iridium (III) complexes: characterization and photophysical properties.
pubmed:affiliation
Department of Chemistry, University of Fribourg, Pérolles, CH-1700 Fribourg, Switzerland.
pubmed:publicationType
Journal Article