15255701

Source:http://linkedlifedata.com/resource/pubmed/id/15255701

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0022634, umls-concept:C0596514
pubmed:issue	15
pubmed:dateCreated	2004-7-16
pubmed:abstractText	[reaction: see text] Bipyridyl(pentamethylcyclopentadienyl)ruthenium chloride is an efficient catalyst for the formal [3,3] rearrangement of allyl beta-ketoesters. The mechanism of the transformation involves formation of pi-allyl ruthenium intermediates, which are selectively attacked at the more substituted allyl terminus by freely diffusing enolates. Decarboxylation of beta-ketocarboxylates allows generation of enolates under extremely mild conditions.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/100890393
pubmed:status	PubMed-not-MEDLINE
pubmed:month	Jul
pubmed:issn	1523-7060
pubmed:author	pubmed-author:BurgerErin CEC, pubmed-author:TungeJon AJA
pubmed:issnType	Print
pubmed:day	22
pubmed:volume	6
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	2603-5
pubmed:year	2004
pubmed:articleTitle	Ruthenium-catalyzed decarboxylative allylation of nonstabilized ketone enolates.
pubmed:affiliation	Department of Chemistry, University of Kansas, Lawrence, Kansas 66045, USA.
pubmed:publicationType	Journal Article