Source:http://linkedlifedata.com/resource/pubmed/id/15180421
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
12
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| pubmed:dateCreated |
2004-6-7
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| pubmed:abstractText |
Crystalline materials have been isolated and characterized from mixing the silver carborane salts Ag(CB(11)H(12)) or Ag[Co(C(2)B(9)H(11))(2)] with nitrile ligands, either terminal acetonitrile or potentially bridging alkanedinitriles. Most of the complexes showed B-H...Ag interactions between the silver center and carborane anion. [Ag(acetonitrile)(2)(CB(11)H(12))] has a hexagonal network structure. [Ag(malonitrile)(2)(CB(11)H(12))] is a discrete dimeric complex, while [Ag(4)(succinonitrile)(5)(CB(11)H(12))(4)], [Ag(glutaronitrile)(2)][Co(C(2)B(9)H(12))(2)], and [Ag(glutaronitrile)[Co(C(2)B(9)H(11))(2)]] all show coordination chain structures. The carborane anions in [Ag(adiponitrile)[Co(C(2)B(9)H(11))(2)]] bridge between Ag centers to give a 3D CdSO(4)-related coordination polymer. The structure of [Ag(malonitrile)(2)](BF(4)) was also determined to have an unusual chiral diamondoid structure with a skewed 2-fold interpenetration.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Jun
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| pubmed:issn |
0020-1669
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| pubmed:author | |
| pubmed:issnType |
Print
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| pubmed:day |
14
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| pubmed:volume |
43
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| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
3663-72
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| pubmed:year |
2004
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| pubmed:articleTitle |
Coordination polymers with carborane anions: silver dinitrile complexes.
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| pubmed:affiliation |
School of Chemistry, University of Leeds, Leeds LS2 9JT, UK.
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| pubmed:publicationType |
Journal Article
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