Source:http://linkedlifedata.com/resource/pubmed/id/15137776
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
19
|
| pubmed:dateCreated |
2004-5-12
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| pubmed:abstractText |
A homochiral microporous material is presented. The phase has 47% permanently porous void volume and is shown to have >1 nm diameter pores with three-dimensional channels using probe molecule sorption. Enantioselective guest sorption is strongly dependent on guest size. The homochiral microporous phase was identified by reactive selection from a first-generation chiral but nonporous framework. Chiral permanent porosity is established by directional noncovalent interactions between framework-forming and nonframework forming components of the stable second-generation material, which become stronger upon loss of the guests from the pore system.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
May
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| pubmed:issn |
0002-7863
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| pubmed:author | |
| pubmed:issnType |
Print
|
| pubmed:day |
19
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| pubmed:volume |
126
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| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
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| pubmed:pagination |
6106-14
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| pubmed:year |
2004
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| pubmed:articleTitle |
Permanent microporosity and enantioselective sorption in a chiral open framework.
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| pubmed:affiliation |
Department of Chemistry, University of Liverpool, Liverpool L69 7ZD, United Kingdom.
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| pubmed:publicationType |
Journal Article
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