Linked Life Data

15100482

Source:http://linkedlifedata.com/resource/pubmed/id/15100482

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
1
pubmed:dateCreated
2004-4-21
pubmed:abstractText
Casein has been pyrolysed to obtain a biochar (28.3% yield), with mostly meso- and macro-pore structure, and a liquid tar product of high yield (37.5%) with the balance as gas (20.9%) and water (13.3%). The elemental composition of the casein tar was: C 66.7%, H 8.3%, N 12.1% and O 12.9% (by difference). The tar sample has been characterised by mass spectrometry, gas chromatography (GC)/MS and heated-probe MS, to give molecular mass distributions for comparison with molecular mass ranges indicated by analytical-scale size-exclusion chromatography (SEC). The tar appeared to be completely soluble in 1-methyl-2-pyrrolidinone (NMP), the solvent used for SEC. It appeared to consist mostly of lower molecular mass fractions with elution times at 18-26 min. GC/MS analysis showed the presence of both aliphatic and aromatic nitrogen-containing components. Neither GC/MS nor heated-probe MS were able to detect more than about half the tar components.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:issn
1469-0667
pubmed:author
pubmed:issnType
Print
pubmed:volume
10
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
101-8
pubmed:dateRevised
2008-11-21
pubmed:meshHeading
pubmed:year
2004
pubmed:articleTitle
Estimation of the molecular mass range of the tar from pyrolysis of casein by gas chromatography-mass spectrometry, probe mass spectrometry and size exclusion chromatography with 1-methyl-2-pyrrolidinone as eluent.
pubmed:affiliation
Institute of Chemistry and Chemical Technology, Mongolian Academy of Sciences, Ulaanbaatar,51, Mongolia.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't