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rdf:type |
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lifeskim:mentions |
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pubmed:issue |
5
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pubmed:dateCreated |
2004-7-2
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pubmed:abstractText |
An unexpected six-membered silacycle was obtained using ring-closing metathesis of diallylsilane 3. The ring size of the compound formed was derived using a 2D 13C-13C inadequate experiment. All proton and carbon-13 resonances were assigned from classical 2D NMR experiments and the proton coupling pattern was clarified. Molecular modeling calculation was then applied using NMR data as constraints, giving the 3D structure of the synthesized compound.
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pubmed:language |
eng
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pubmed:journal |
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pubmed:citationSubset |
IM
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pubmed:chemical |
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pubmed:status |
MEDLINE
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pubmed:month |
May
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pubmed:issn |
0749-1581
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pubmed:author |
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pubmed:copyrightInfo |
Copyright 2004 John Wiley & Sons, Ltd.
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pubmed:issnType |
Print
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pubmed:volume |
42
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
467-73
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pubmed:dateRevised |
2006-11-15
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pubmed:meshHeading |
pubmed-meshheading:15095383-Algorithms,
pubmed-meshheading:15095383-Allyl Compounds,
pubmed-meshheading:15095383-Computer Simulation,
pubmed-meshheading:15095383-Crystallography,
pubmed-meshheading:15095383-Magnetic Resonance Spectroscopy,
pubmed-meshheading:15095383-Models, Chemical,
pubmed-meshheading:15095383-Models, Molecular,
pubmed-meshheading:15095383-Molecular Conformation,
pubmed-meshheading:15095383-Organophosphorus Compounds,
pubmed-meshheading:15095383-Reproducibility of Results,
pubmed-meshheading:15095383-Sensitivity and Specificity,
pubmed-meshheading:15095383-Silanes,
pubmed-meshheading:15095383-Stereoisomerism
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pubmed:year |
2004
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pubmed:articleTitle |
Multinuclear magnetic resonance and molecular modeling investigations as unambiguous methods for the determination of silacycle 3D structures.
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pubmed:affiliation |
Laboratoire de Chimie Organique et Organométallique, UMR CNRS 5802, Talence, France.
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pubmed:publicationType |
Journal Article,
Comparative Study,
Evaluation Studies,
Validation Studies
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