Linked Life Data

15065781

Source:http://linkedlifedata.com/resource/pubmed/id/15065781

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
1-2
pubmed:dateCreated
2004-4-6
pubmed:abstractText
Ethylenediaminetetraacetic acid (EDTA) is a metal complexing agent which is commonly used for removing metallic surface contaminations. But its presence in aqueous industrial effluents or in wastes, by example those which are generated from nuclear power facilities, is forbidden or strictly regulated by the legislation. The implementation of high-performance liquid chromatography coupled with mass spectrometry (MS) via an electrospray interface has exhibited a powerful capacity in the measurement of this complexing agent, in the form of its iron complex. The complex is eluted through a reversed stationary phase under slightly acidic conditions and the detection is performed by mass spectrometry in the single ion monitoring mode. This technique has allowed us to reach a detection limit of about 1 microg/l in EDTA for only 20 microl injected without any previous preconcentration, and to solve some analytical interferences observed in the case of industrial effluents with other analytical techniques such as ion chromatography.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Apr
pubmed:issn
0021-9673
pubmed:author
pubmed:issnType
Print
pubmed:day
2
pubmed:volume
1032
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
87-92
pubmed:dateRevised
2009-1-15
pubmed:meshHeading
pubmed:year
2004
pubmed:articleTitle
Determination of ethylenediaminetetraacetic acid at very low concentrations by high-performance liquid chromatography coupled with electrospray mass spectrometry.
pubmed:affiliation
Département d'Etudes des Déchets, Direction de l'Energie Nucléaire, C.E.A. Cadarache, 13108 Saint Paul lez Durance, France. alain.dodi@cea.fr
pubmed:publicationType
Journal Article