Source:http://linkedlifedata.com/resource/pubmed/id/15040731
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
7
|
| pubmed:dateCreated |
2004-3-25
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| pubmed:abstractText |
A [2]catenane in which the macrocyclic polyether, bisparaphenylene[34]crown-10, is interlocked with the tetracationic cyclophane, cyclobis(paraquat-p-phenylene), is shown by dynamic (1)H NMR spectroscopy, using (i). neutral and (ii). anionic chiral shift reagents (CSRs), to exist at low temperatures (197 K) in acetone-d(6) solutions as 1:1 and 2:1 mixtures of diastereoisomeric complexes and salts, respectively, as a consequence of the helical chirality associated with the [2]catenane interacting with the CSRs.
|
| pubmed:language |
eng
|
| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
|
| pubmed:month |
Apr
|
| pubmed:issn |
1523-7060
|
| pubmed:author | |
| pubmed:issnType |
Print
|
| pubmed:day |
1
|
| pubmed:volume |
6
|
| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
|
| pubmed:pagination |
1095-8
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| pubmed:year |
2004
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| pubmed:articleTitle |
Helical chirality in donor-acceptor catenanes.
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| pubmed:affiliation |
Department of Chemistry and Biochemistry, University of California, Los Angeles, 405 Hilgard Avenue, Los Angeles, California 90095-1569, USA.
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| pubmed:publicationType |
Journal Article
|