Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
3
pubmed:dateCreated
2004-3-11
pubmed:abstractText
We present local velocity measurements in emulsions under shear using heterodyne Dynamic Light Scattering. Two emulsions are studied: a dilute system of volume fraction phi = 20% and a concentrated system with phi = 75%. Velocity profiles in both systems clearly show the presence of wall slip. We investigate the evolution of slip velocities as a function of shear stress and discuss the validity of the corrections for wall slip classically used in rheology. Focussing on the bulk flow, we show that the dilute system is Newtonian and that the concentrated emulsion is shear-thinning. In the latter case, the curvature of the velocity profiles is compatible with a shear-thinning exponent of 0.4 consistent with global rheological data. However, even if individual profiles can be accounted for by a power law fluid (with or without a yield stress), we could not find a fixed set of parameters that would fit the whole range of applied shear rates. Our data, thus, raise the question of the definition of a global flow curve for such a concentrated system. These results show that local measurements are a crucial complement to standard rheological tools. They are discussed in the light of recent works on soft glassy materials.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Mar
pubmed:issn
1292-8941
pubmed:author
pubmed:issnType
Print
pubmed:volume
10
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
209-21
pubmed:dateRevised
2006-11-15
pubmed:meshHeading
pubmed:year
2003
pubmed:articleTitle
Towards local rheology of emulsions under Couette flow using Dynamic Light Scattering.
pubmed:affiliation
Centre de Recherche Paul Pascal, Avenue Schweitzer, 33600 Pessac, France. salmon@crpp.u-bordeaux.fr
pubmed:publicationType
Journal Article