Source:http://linkedlifedata.com/resource/pubmed/id/14993949
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
3
|
| pubmed:dateCreated |
2004-3-2
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| pubmed:abstractText |
The photodecarboxylation reactions of omega-phthalimidoalkynoates have been studied and the influence of the geometrically restricted acetylene linker on the photocyclization efficiency investigated. Less flexible starting materials give solely CO(2)H/H-exchange products in good yields. In contrast, derivatives with appropriate chain lengths give the corresponding macrocycles in fair to moderate isolated yields. Furthermore, photodecarboxylative addition of alkynoates to N-methylphthalimide gives hydroxyphthalimidines in acceptable yields.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
|
| pubmed:month |
Mar
|
| pubmed:issn |
1474-905X
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| pubmed:author | |
| pubmed:issnType |
Print
|
| pubmed:volume |
3
|
| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
|
| pubmed:pagination |
311-6
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| pubmed:year |
2004
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| pubmed:articleTitle |
Synthesis of cycloalkynes via photochemical decarboxylation of omega-phthalimidoalkynoates.
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| pubmed:affiliation |
Department of Chemistry, Seonam University, 720 Gwangchi-Dong, Namwon-Si, Chonbuk 590-711, Korea. djyoo@seonam.ac.kr
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| pubmed:publicationType |
Journal Article
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