Source:http://linkedlifedata.com/resource/pubmed/id/14986942
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
5
|
| pubmed:dateCreated |
2004-2-27
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| pubmed:abstractText |
A template-directed strategy to forming a bis(diimide) macrocycle through an intermediate asymmetric [2]catenane is reported. Saponification of the ester linkages within the crown ether component is much slower in the mechanically interlocked structure when compared to the free crown. The predominance of a single translational isomer leads to a dimeric structure, resulting in the generation of infinite channels within the crystal lattice. [structure: see text]
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| pubmed:language |
eng
|
| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
|
| pubmed:month |
Mar
|
| pubmed:issn |
1523-7060
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| pubmed:author | |
| pubmed:issnType |
Print
|
| pubmed:day |
4
|
| pubmed:volume |
6
|
| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
|
| pubmed:pagination |
655-8
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| pubmed:year |
2004
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| pubmed:articleTitle |
Unusual solid-state behavior in a neutral [2]catenane bearing a hydrolyzable component.
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| pubmed:affiliation |
School of Chemistry and Centre for Green Chemistry, Monash University, Clayton, Victoria 3800, Australia.
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| pubmed:publicationType |
Journal Article
|