Linked Life Data

14737222

Source:http://linkedlifedata.com/resource/pubmed/id/14737222

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
12
pubmed:dateCreated
2004-1-22
pubmed:abstractText
Polymer microchannel chips (depth 20 microm and width 100 microm) integrated with band electrodes were fabricated by photolithography and imprinting methods, and applied to a spectroelectrochemical study on the cation radical of perylene (Pe). A propylene carbonate solution of Pe was brought into the channel chip by pressure driven flow and Pe was oxidized at the working band electrode (WE) in the channel. Simultaneously, absorption measurements of the solution phase in the downstream side of the electrode (30 microm from WE) were conducted on the basis of space resolved spectroscopy. The decrease in the absorbance of Pe at 438 nm upon electrolysis accompanied an appearance of the absorption band around 538 nm, which was assigned to that of the Pe cation radical. When the perylene solution was introduced to the microchip at a slow flow velocity, the dimer cation radical of Pe was shown to be produced in the channel chip. The formation and disappearance processes of the monomer and dimer cation radicals of Pe in the channel were followed by flow velocity and position dependencies of the absorption spectra.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Dec
pubmed:issn
0003-2654
pubmed:author
pubmed:issnType
Print
pubmed:volume
128
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
1401-5
pubmed:year
2003
pubmed:articleTitle
A spectroelectrochemical study on perylene cation radical in polymer microchannel-microelectrode chips.
pubmed:affiliation
Division of Chemistry, Graduate School of Science, Hokkaido University, Sapporo 060-0810, Japan.
pubmed:publicationType
Journal Article