Source:http://linkedlifedata.com/resource/pubmed/id/14719908
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
2
|
| pubmed:dateCreated |
2004-1-14
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| pubmed:abstractText |
On irradiation of p-chloranil (CA), 2,2-bis(p-methoxyphenyl)-3,3-dimethyl-4-methylenecyclobutanone (1) gives 2,2-bis(p-methoxyphenyl)-4-isopropylidenecyclobutanone (2), whereas 2 affords a CA adduct (4), suggesting that a novel rearrangement of 1 to give 2 occurs irreversibly via intermediate 3*+, a radical cation variant of an unprecedented oxa analogue of tetramethyleneethane.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
|
| pubmed:month |
Jan
|
| pubmed:issn |
0002-7863
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| pubmed:author | |
| pubmed:issnType |
Print
|
| pubmed:day |
21
|
| pubmed:volume |
126
|
| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
|
| pubmed:pagination |
414-5
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| pubmed:dateRevised |
2008-1-17
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| pubmed:year |
2004
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| pubmed:articleTitle |
Rearrangement of a 2-methylenecyclobutanone derivative triggered by photoinduced electron transfer: an unprecedented oxa analogue of the tetramethyleneethane radical cation.
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| pubmed:affiliation |
Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan. ikeda@org.chem.tohoku.ac.jp
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| pubmed:publicationType |
Journal Article
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