Source:http://linkedlifedata.com/resource/pubmed/id/14712023
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
Pt 1
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| pubmed:dateCreated |
2004-1-8
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| pubmed:abstractText |
In the title complex, [Co(2)(C(10)H(2)O(8))(C(10)H(8)N(2))(2)(H(2)O)(2)], the four carboxylate groups are fully deprotonated and coordinate to four Co(II) cations in a monodentate fashion, forming a one-dimensional ribbon-like double-chain structure, with centrosymmetric [Co(2)(C(10)H(2)O(8))(C(10)H(8)N(2))(2)(H(2)O)(2)] repeating units and a cavity of approximately 6.8 x 6.6 A. Moreover, a three-dimensional supramolecular structure is formed by face-to-face pi-pi interactions between the aromatic rings of the 2,2'-bipyridine moieties of two adjacent chains, and by hydrogen-bonding interactions between the coordinated aqua O atom and the coordinated carboxyl O atom from different chains.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Jan
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| pubmed:issn |
0108-2701
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| pubmed:author | |
| pubmed:issnType |
Print
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| pubmed:volume |
60
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| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
m16-7
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| pubmed:year |
2004
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| pubmed:articleTitle |
Catena-poly[bis[aqua(2,2-bipyridine-kappa 2N,N')cobalt(II)]-mu-1,2,4,5-benzenetetracarboxylato-kappa 4O1:O2:O3:O4].
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| pubmed:affiliation |
Department of Chemistry and Materials Science, Wenzhou Normal College, Wenzhou 325027, People's Republic of China. xhpch@163.com
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| pubmed:publicationType |
Journal Article
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