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PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
20
pubmed:dateCreated
2003-12-19
pubmed:abstractText
We change the diffusion mechanism of adsorbed Ge-Si dimers on Si(001) using the electric field of a scanning tunneling microscope tip. By comparing the measured field dependence with first-principles calculations we conclude that, in negative field, i.e., when electrons are attracted towards the vacuum, the dimer diffuses as a unit, rotating as it translates, whereas, in positive field the dimer bond is substantially stretched at the transition state as it slides along the substrate. Furthermore, the active mechanism in positive fields facilitates intermixing of Ge in the Si lattice, whereas intermixing is suppressed in negative fields.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Nov
pubmed:issn
0031-9007
pubmed:author
pubmed:issnType
Print
pubmed:day
14
pubmed:volume
91
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
206104
pubmed:year
2003
pubmed:articleTitle
Changing the diffusion mechanism of Ge-Si dimers on Si(001) using an electric field.
pubmed:affiliation
Sandia National Laboratories, Albuquerque, New Mexico 87185, USA.
pubmed:publicationType
Journal Article