Source:http://linkedlifedata.com/resource/pubmed/id/14682770
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Predicate | Object |
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
26
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pubmed:dateCreated |
2003-12-19
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pubmed:abstractText |
The major cuticular hydrocarbons from the cane beetle species Antitrogus parvulus were deduced to be 4,6,8,10,16,18-hexa- and 4,6,8,10,16-pentamethyldocosanes 2 and 3, respectively. Isomers of 2,4,6,8-tetramethylundecanal 27, 36, and 37, derived from 2,4,6-trimethylphenol, were coupled with the phosphoranes 28 and 29 to furnish alkenes and, by reduction, diastereomers of 2 and 3. Chromatographic and spectroscopic comparisons confirmed 2 as either 6a or 6b and 3 as either 34a or 34b. [structure: see text]
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pubmed:language |
eng
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pubmed:journal | |
pubmed:citationSubset |
IM
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pubmed:chemical | |
pubmed:status |
MEDLINE
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pubmed:month |
Dec
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pubmed:issn |
1523-7060
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pubmed:author | |
pubmed:issnType |
Print
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pubmed:day |
25
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pubmed:volume |
5
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
5083-6
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pubmed:dateRevised |
2006-11-15
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pubmed:meshHeading |
pubmed-meshheading:14682770-Alkanes,
pubmed-meshheading:14682770-Animals,
pubmed-meshheading:14682770-Beetles,
pubmed-meshheading:14682770-Female,
pubmed-meshheading:14682770-Hydrocarbons,
pubmed-meshheading:14682770-Isomerism,
pubmed-meshheading:14682770-Magnetic Resonance Spectroscopy,
pubmed-meshheading:14682770-Molecular Conformation
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pubmed:year |
2003
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pubmed:articleTitle |
4,6,8,10,16-penta- and 4,6,8,10,16,18-hexamethyldocosanes from the cane beetle antitrogusparvulus--cuticular hydrocarbons with unprecedented structure and stereochemistry.
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pubmed:affiliation |
Department of Chemistry, University of Queensland, Brisbane, Australia.
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pubmed:publicationType |
Journal Article,
Research Support, Non-U.S. Gov't
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