Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
51
pubmed:dateCreated
2003-12-17
pubmed:abstractText
A novel synthetic approach to a series of bulky triarylamines substituted by various electron-withdrawing groups and forming amorphous materials is presented. Under vacuum evaporation, thin films with high optical quality are obtained and exhibit spontaneous second-order nonlinear optical activity. This unprecedented result is likely due to subtle balance between strong dipole-dipole interactions and steric crowding causing self-assembly and noncentrosymmetric local ordering, stable up to one year.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Dec
pubmed:issn
0002-7863
pubmed:author
pubmed:issnType
Print
pubmed:day
24
pubmed:volume
125
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
15744-5
pubmed:dateRevised
2008-1-17
pubmed:year
2003
pubmed:articleTitle
Versatile synthesis of small NLO-active molecules forming amorphous materials with spontaneous second-order NLO response.
pubmed:affiliation
ENS Cachan, PPSM (CNRS UMR 8531), 61 avenue du Président Wilson, 94235 Cachan Cedex, France. ishow2ppsm.ens-cachan.fr
pubmed:publicationType
Journal Article