Source:http://linkedlifedata.com/resource/pubmed/id/14624560
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
47
|
| pubmed:dateCreated |
2003-11-19
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| pubmed:abstractText |
The reactivities of (C5Me5)3U and (C5Me4H)3U were compared using both common (THF) and nontraditional (N2) ligands for f elements. THF coordinates the less-crowded (C5Me4H)3U to form (C5Me4H)3U(THF) while ring opening occurs with sterically crowded (C5Me5)3U. N2 at 80 psi reacts with (C5Me5)3U to form (C5Me5)3U(eta1-N2) [U-N(N2) = 2.492(10) A, nu(N2) = 2207 cm-1, and cnt-U-N2 = 90 degrees ], whereas only (C5Me4H)3U was isolated under 80 psi of N2.
|
| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
|
| pubmed:month |
Nov
|
| pubmed:issn |
0002-7863
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| pubmed:author | |
| pubmed:issnType |
Print
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| pubmed:day |
26
|
| pubmed:volume |
125
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| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
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| pubmed:pagination |
14264-5
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| pubmed:dateRevised |
2008-1-17
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| pubmed:year |
2003
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| pubmed:articleTitle |
A monometallic f element complex of dinitrogen: (C5Me5)3U(eta1-N2).
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| pubmed:affiliation |
Department of Chemistry, University of California, Irvine, CA 92697-2025, USA. wevans@uci.edu
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| pubmed:publicationType |
Journal Article
|