Source:http://linkedlifedata.com/resource/pubmed/id/14583000
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Predicate | Object |
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
44
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pubmed:dateCreated |
2003-10-29
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pubmed:abstractText |
The perimidine skeleton provides a framework for the isolation of a novel, stable carbene possessing a unique molecular architecture and electronic structure. The remarkable steric environment and exceptional electron-donating ability for the carbene-carbon are revealed through structural and spectroscopic characterization of the parent carbene and two sterically encumbered rhodium-carbene complexes, L2RhCl{C[NCH(CH3)2]2(C10H6)} (5 L2 = COD; 6 L = CO).
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pubmed:language |
eng
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pubmed:journal | |
pubmed:status |
PubMed-not-MEDLINE
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pubmed:month |
Nov
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pubmed:issn |
0002-7863
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pubmed:author | |
pubmed:issnType |
Print
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pubmed:day |
5
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pubmed:volume |
125
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
13314-5
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pubmed:dateRevised |
2008-1-17
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pubmed:year |
2003
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pubmed:articleTitle |
Constructing a stable carbene with a novel topology and electronic framework.
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pubmed:affiliation |
Department of Chemistry and the Center for Catalysis Research and Innovation, University of Ottawa, Ottawa, Ontario, Canada K1N 6N5.
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pubmed:publicationType |
Journal Article
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