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14572290
Source:
http://linkedlifedata.com/resource/pubmed/id/14572290
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rdf:type
pubmed:Citation
lifeskim:mentions
umls-concept:C0010546
,
umls-concept:C0037638
,
umls-concept:C0914356
,
umls-concept:C1280500
,
umls-concept:C1883254
,
umls-concept:C2603343
pubmed:issue
22
pubmed:dateCreated
2003-10-23
pubmed:abstractText
[reaction: see text]. The intramolecular vinylogous Morita-Baylis-Hillman reaction was explored to access the central cyclopentane ring of FR182877. The reaction manifold and product distribution is strikingly solvent and substrate dependent.
pubmed:grant
http://linkedlifedata.com/resource/pubmed/grant/CA 96376
,
http://linkedlifedata.com/resource/pubmed/grant/GM 26782
pubmed:language
eng
pubmed:journal
http://linkedlifedata.com/resource/pubmed/journal/100890393
pubmed:citationSubset
IM
pubmed:chemical
http://linkedlifedata.com/resource/pubmed/chemical/FR 182877
,
http://linkedlifedata.com/resource/pubmed/chemical/Organotin Compounds
,
http://linkedlifedata.com/resource/pubmed/chemical/Phosphines
,
http://linkedlifedata.com/resource/pubmed/chemical/Polycyclic Compounds
,
http://linkedlifedata.com/resource/pubmed/chemical/Solvents
,
http://linkedlifedata.com/resource/pubmed/chemical/trimethyl phosphine
,
http://linkedlifedata.com/resource/pubmed/chemical/vinyltributylstannane
pubmed:status
MEDLINE
pubmed:month
Oct
pubmed:issn
1523-7060
pubmed:author
pubmed-author:MethotJoey LJL
,
pubmed-author:RoushWilliam RWR
pubmed:issnType
Print
pubmed:day
30
pubmed:volume
5
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
4223-6
pubmed:dateRevised
2007-11-14
pubmed:meshHeading
pubmed-meshheading:14572290-Catalysis
,
pubmed-meshheading:14572290-Cyclization
,
pubmed-meshheading:14572290-Molecular Conformation
,
pubmed-meshheading:14572290-Molecular Structure
,
pubmed-meshheading:14572290-Organotin Compounds
,
pubmed-meshheading:14572290-Phosphines
,
pubmed-meshheading:14572290-Polycyclic Compounds
,
pubmed-meshheading:14572290-Solvents
pubmed:year
2003
pubmed:articleTitle
Synthetic studies toward FR182877. Remarkable solvent effect in the vinylogous morita-baylis-hillman cyclization.
pubmed:affiliation
Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109, USA.
pubmed:publicationType
Journal Article
,
Research Support, U.S. Gov't, P.H.S.