Linked Life Data

14524801

Source:http://linkedlifedata.com/resource/pubmed/id/14524801

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
3 Pt 1
pubmed:dateCreated
2003-10-3
pubmed:abstractText
The driving force dependence of photoinduced electron transfer rate constant in synthetic DNA hairpins in aqueous solutions has been analyzed by means of molecular dynamics simulations. The quantum energy gap law has thus been investigated from a fully atomistic point of view, well reproducing the experimental results with reduced ambiguities in the parameter fitting. Although the contribution from the high-frequency vibrational modes of DNA and water solvent to the reorganization energy is fairly small, their quantum effect on the electron transfer rate constant is significant, well accounting for the deviation from the Marcus parabola observed in the experiments.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Sep
pubmed:issn
1539-3755
pubmed:author
pubmed:issnType
Print
pubmed:volume
68
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
031905
pubmed:dateRevised
2006-11-15
pubmed:meshHeading
pubmed:year
2003
pubmed:articleTitle
Nuclear quantum effects on electron transfer reactions in DNA hairpins.
pubmed:affiliation
Advanced Materials & Devices Laboratory, Corporate R & D Center, Toshiba Corporation, Kawasaki 212-8582, Japan. tanaka2@arl.rdc.toshiba.co.jp
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't