Linked Life Data

14499840

Source:http://linkedlifedata.com/resource/pubmed/id/14499840

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
12
pubmed:dateCreated
2003-9-22
pubmed:abstractText
The bilirubinIXalpha and its neutral calcium bilirubinate were studied using Raman spectroscopy at high external pressure. The results showed that the bilirubinIXalpha has two pressure-induced phase transitions (15-18 and 30-36 kbar) and three pressure phase areas. Its pressure sensitivities in the low-pressure phase are very low. It is believed that the four internally hydrogen bonds in bilirubinIXalpha molecule cause the atoms to attract each other tightly in the bilirubinIXalpha molecule. Therefore, the low pressure is not strong enough to shorten the bonds significantly. The pressure sensitivities in the middle-pressure phase are much higher than those in the low-pressure phase, but those in the high-pressure phase are slightly lower than in the middle-pressure phase. There is only one pressure-induced phase transition (25-34 kbar) in the neutral calcium bilirubinate. The pressure sensitivities in the low-pressure phase are higher than those in the high-pressure phase as usually.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Oct
pubmed:issn
1386-1425
pubmed:author
pubmed:issnType
Print
pubmed:volume
59
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
2791-6
pubmed:dateRevised
2006-11-15
pubmed:meshHeading
pubmed:year
2003
pubmed:articleTitle
The pressure tunning Raman spectral studies of the bilirubinIXalpha and neutral calcium bilirubinate at high external pressure.
pubmed:affiliation
State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China. zhcxu@pku.edu.cn
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't