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rdf:type |
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lifeskim:mentions |
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pubmed:issue |
11
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pubmed:dateCreated |
1993-2-8
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pubmed:abstractText |
Zinc triflate was found to be superior to the heavy metal salts as a promoter in the Koenigs-Knorr type glycosidation reaction in the synthesis of lipid A disaccharide intermediates. It readily promoted the reaction of a complex glycosyl bromide with a reducing sugar moiety and gave the disaccharide with beta-selectivity in good yield. This method would be suitable for the bulk preparation of lipid A disaccharide intermediates.
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pubmed:language |
eng
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pubmed:journal |
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pubmed:citationSubset |
IM
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pubmed:chemical |
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pubmed:status |
MEDLINE
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pubmed:month |
Nov
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pubmed:issn |
0009-2363
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pubmed:author |
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pubmed:issnType |
Print
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pubmed:volume |
40
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
2909-12
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pubmed:dateRevised |
2006-11-15
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pubmed:meshHeading |
pubmed-meshheading:1335843-Carbohydrate Sequence,
pubmed-meshheading:1335843-Chromatography, Thin Layer,
pubmed-meshheading:1335843-Disaccharides,
pubmed-meshheading:1335843-Glycosylation,
pubmed-meshheading:1335843-Lipid A,
pubmed-meshheading:1335843-Magnetic Resonance Spectroscopy,
pubmed-meshheading:1335843-Mass Spectrometry,
pubmed-meshheading:1335843-Mesylates,
pubmed-meshheading:1335843-Molecular Sequence Data,
pubmed-meshheading:1335843-Spectrophotometry, Infrared,
pubmed-meshheading:1335843-Zinc
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pubmed:year |
1992
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pubmed:articleTitle |
Zinc triflate-promoted glycosidation: synthesis of lipid A disaccharide intermediates.
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pubmed:affiliation |
Exploratory Research Laboratories I, Daiichi Pharmaceutical Co. Ltd., Tokyo, Japan.
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pubmed:publicationType |
Journal Article
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