Source:http://linkedlifedata.com/resource/pubmed/id/12940050
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Predicate | Object |
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
1
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pubmed:dateCreated |
2003-8-27
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pubmed:abstractText |
A new method for on-line solvent extraction covalent hydride generation in a non-aqueous media was proposed. Flow injection techniques were used to develop an efficient on-line solvent extraction pre-concentration and pre-separation system. The hydride generation is carried out in an aliquot of metal-complex extraction solution by sodium tetrahydroborate(III) in N,N-dimethyl formamide solution and anhydrons acetic acid. Hg is extracted by KI + HNO3 + (NH2)2CS into TBP and hydride generation by proposed method. A improved u-type gas-liguid separator was used. The working conditions and manifolds scheme of flow injection had been optimized. The method is applied to the determination of mercury in GSD-4 and GSD-6 geological reference materials with good accuracy and precision.
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pubmed:language |
chi
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pubmed:journal | |
pubmed:citationSubset |
IM
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pubmed:chemical | |
pubmed:status |
MEDLINE
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pubmed:month |
Feb
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pubmed:issn |
1000-0593
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pubmed:author | |
pubmed:issnType |
Print
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pubmed:volume |
22
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
131-4
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pubmed:dateRevised |
2006-11-15
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pubmed:meshHeading |
pubmed-meshheading:12940050-Borohydrides,
pubmed-meshheading:12940050-Flow Injection Analysis,
pubmed-meshheading:12940050-Mercury,
pubmed-meshheading:12940050-Oxidation-Reduction,
pubmed-meshheading:12940050-Sensitivity and Specificity,
pubmed-meshheading:12940050-Spectrometry, Fluorescence,
pubmed-meshheading:12940050-Spectrophotometry, Atomic
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pubmed:year |
2002
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pubmed:articleTitle |
[Study and application of flow injection liquid-liquid extraction non-aqueous media mercury reduction atomic fluorescence spectrometry].
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pubmed:affiliation |
National Laboratory of Coal Combustion, Huazhong University of Science and Technology, Wuhan 430074, China.
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pubmed:publicationType |
Journal Article,
English Abstract
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