Linked Life Data

12932473

Source:http://linkedlifedata.com/resource/pubmed/id/12932473

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
1
pubmed:dateCreated
2003-8-22
pubmed:abstractText
Spin-state selection in solid-state NMR is demonstrated, using similar pulse sequences as used in liquid-state NMR. The different transitions of all three carbon resonances in fully 13C-labeled L-alanine are separated in different spectra. By selecting spin-states, the contribution of the J-coupling to the linewidth is removed, leading to a considerable enhancement in resolution. The spin-state-selective technique is demonstrated for magic-angle spinning frequencies from 6 to 35kHz. Other experimental conditions affecting the sensitivity of the experiments are discussed. Sensitivity losses due to the introduction of the spin-state-selective filter are shown to be acceptable. Finally, spin-state selection was used to experimentally confirm the differential broadening expected for the two transitions of the CH3 resonance.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Sep
pubmed:issn
1090-7807
pubmed:author
pubmed:issnType
Print
pubmed:volume
164
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
187-95
pubmed:meshHeading
pubmed:year
2003
pubmed:articleTitle
Spin-state selection in solid-state NMR.
pubmed:affiliation
Laboratoire de Chimie (UMR-5532 CNRS/ENS), Laboratoire de Recherche Conventionné du CEA (23V), Ecole Normale Supérieure de Lyon, 46 Allée d'Italie, 69364 Lyon, France.
pubmed:publicationType
Journal Article, Evaluation Studies, Validation Studies