Source:http://linkedlifedata.com/resource/pubmed/id/12924554
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
1-2
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| pubmed:dateCreated |
2003-8-19
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| pubmed:abstractText |
A rapid multiresidue method has been developed for the analysis of carbamate insecticides (oxamyl, methomyl, propoxur, carbofuran, carbaryl and methiocarb) in soil. The method is based on the sonication-assisted extraction of soil samples placed in small columns using a low volume of methanol. Residue levels in soil were determined by reversed-phase high-performance liquid chromatography with fluorescence detection after post-column derivatisation. The separation of carbamates is performed on a C8 column with water-methanol as mobile phase. Recovery studies were carried out at 0.5, 0.1 and 0.01 microg/g fortification levels and average recoveries obtained for carbamates ranged from 82 to 99% with relative standard deviations between 0.4 and 10%. The effect of residue residence time and soil moisture content on the insecticide recovery was also studied. The method is linear over the range assayed, from 0.1 to 1 microg/ml. The detection limit for the carbamates varied from 1.6 to 3.7 microg/kg and the quantification limit obtained was 10 microg/kg. The emission and excitation allowed the confirmation of residues at levels around 0.1 microg/g.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:citationSubset |
IM
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| pubmed:chemical | |
| pubmed:status |
MEDLINE
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| pubmed:month |
Jul
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| pubmed:issn |
0021-9673
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| pubmed:author | |
| pubmed:issnType |
Print
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| pubmed:day |
25
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| pubmed:volume |
1007
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| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
85-91
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| pubmed:dateRevised |
2009-1-15
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| pubmed:meshHeading | |
| pubmed:year |
2003
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| pubmed:articleTitle |
Multiresidue analysis of carbamate pesticides in soil by sonication-assisted extraction in small columns and liquid chromatography.
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| pubmed:affiliation |
Departamento de Medio Ambiente, INIA, Carretera de La Coruña, Km 7, 28040 Madrid, Spain.
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| pubmed:publicationType |
Journal Article
|