12917003

Source:http://linkedlifedata.com/resource/pubmed/id/12917003

Download in:

Switch to

Custom View

Named Graph Language Inference

Statements in which the resource exists as a subject.
Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0007382, umls-concept:C0439851, umls-concept:C0443286, umls-concept:C1552596, umls-concept:C1947931
pubmed:issue	17
pubmed:dateCreated	2003-8-14
pubmed:abstractText	[reaction: see text] A copper fluoride-catalyzed cyanomethylation that can be applied to a wide range of ketones and aldehydes was developed using TMSCH(2)CN as a nucleophile. The reaction was extended to a conceptually more advanced copper alkoxide-catalyzed direct addition of alkylnitriles to aldehydes, which can act as a surrogate direct catalytic aldol reaction of esters. These reactions can be applied to the first catalytic enantioselective cyanomethylation of ketones and direct catalytic enantioselective cyanomethylation of aldehydes.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/100890393
pubmed:status	PubMed-not-MEDLINE
pubmed:month	Aug
pubmed:issn	1523-7060
pubmed:author	pubmed-author:KanaiMotomuM, pubmed-author:KumagaiNaoyaN, pubmed-author:MatsunagaShigekiS, pubmed-author:ShibasakiMasakatsuM, pubmed-author:SutoYutakaY
pubmed:issnType	Print
pubmed:day	21
pubmed:volume	5
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	3147-50
pubmed:year	2003
pubmed:articleTitle	Direct catalytic aldol-type reactions using RCH2CN.
pubmed:affiliation	Graduate School of Pharmaceutical Sciences, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.
pubmed:publicationType	Journal Article