12790550

Source:http://linkedlifedata.com/resource/pubmed/id/12790550

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0002078, umls-concept:C0020930, umls-concept:C0220781, umls-concept:C0332514, umls-concept:C1704241, umls-concept:C1720127, umls-concept:C1883254
pubmed:issue	12
pubmed:dateCreated	2003-6-6
pubmed:abstractText	[reaction: see text] The reaction of a divalent titanium reagent Ti(O-i-Pr)(4)/2i-PrMgX with optically active arylaldimines derived from arylaldehydes and O-methylphenylglycinol provided, in a highly diastereoselective manner, chiral (eta(2)-imine)Ti(O-i-Pr)(2) complexes, which in turn reacted with 1-alkynes or propargyl compounds to give optically active allyl- and alpha-allenylamines, respectively.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/100890393
pubmed:status	PubMed-not-MEDLINE
pubmed:month	Jun
pubmed:issn	1523-7060
pubmed:author	pubmed-author:FukuharaKohkiK, pubmed-author:IlligJ JJJ, pubmed-author:OkamotoSentaroS
pubmed:issnType	Print
pubmed:day	12
pubmed:volume	5
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	2145-8
pubmed:year	2003
pubmed:articleTitle	Asymmetric synthesis of allyl- and alpha-allenylamines from chiral imines and alkynes via (eta(2)-imine)Ti(O-i-Pr)2 complexes.
pubmed:affiliation	Graduate School of Bioscience and Biotechnology, Tokyo Institute of Technology, 4259 Nagatsuta-cho, Midori-ku, Yokohama, Kanagawa 226-8501, Japan.
pubmed:publicationType	Journal Article