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rdf:type
lifeskim:mentions
pubmed:issue
19
pubmed:dateCreated
2003-6-5
pubmed:abstractText
Dynamics of five supercooled molecular liquids have been studied using optical heterodyne detected optical Kerr effect experiments. "Intermediate" time scale power law decays (approximately 2 ps to 1-10 ns) with temperature independent exponents close to -1 have been observed in all five samples from high temperature to approximately T(c), the mode-coupling theory (MCT) critical temperature. The amplitude of the intermediate power law increases with temperature as [(T-T(c))/T(c)](1/2). The results cannot be explained by standard MCT, and one possible explanation within MCT would require the higher order singularity scenario, thought to be highly improbable, to be virtually universal.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
May
pubmed:issn
0031-9007
pubmed:author
pubmed:issnType
Print
pubmed:day
16
pubmed:volume
90
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
197401
pubmed:year
2003
pubmed:articleTitle
Experimental observation of a nearly logarithmic decay of the orientational correlation function in supercooled liquids on the picosecond-to-nanosecond time scales.
pubmed:affiliation
Department of Chemistry, Stanford University, Stanford, California 94305, USA.
pubmed:publicationType
Journal Article