Source:http://linkedlifedata.com/resource/pubmed/id/12785982
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
19
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pubmed:dateCreated |
2003-6-5
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pubmed:abstractText |
Dynamics of five supercooled molecular liquids have been studied using optical heterodyne detected optical Kerr effect experiments. "Intermediate" time scale power law decays (approximately 2 ps to 1-10 ns) with temperature independent exponents close to -1 have been observed in all five samples from high temperature to approximately T(c), the mode-coupling theory (MCT) critical temperature. The amplitude of the intermediate power law increases with temperature as [(T-T(c))/T(c)](1/2). The results cannot be explained by standard MCT, and one possible explanation within MCT would require the higher order singularity scenario, thought to be highly improbable, to be virtually universal.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:status |
PubMed-not-MEDLINE
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pubmed:month |
May
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pubmed:issn |
0031-9007
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pubmed:author | |
pubmed:issnType |
Print
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pubmed:day |
16
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pubmed:volume |
90
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
197401
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pubmed:year |
2003
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pubmed:articleTitle |
Experimental observation of a nearly logarithmic decay of the orientational correlation function in supercooled liquids on the picosecond-to-nanosecond time scales.
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pubmed:affiliation |
Department of Chemistry, Stanford University, Stanford, California 94305, USA.
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pubmed:publicationType |
Journal Article
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