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rdf:type |
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|
lifeskim:mentions |
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pubmed:issue |
5
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pubmed:dateCreated |
2003-5-8
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pubmed:abstractText |
The reaction of the dianion of phenylsulfinylacetone with alkyl halides afforded beta-keto sulfoxides, which were first chlorinated with hexachloroethane and then treated successively with KH and t-BuLi to give carboxylic acids in three-steps in moderate overall yields from the alkyl halides. This procedure affords a good method for a synthesis of carboxylic acids from alkyl halides with three-carbon elongation.
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pubmed:language |
eng
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pubmed:journal |
|
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pubmed:citationSubset |
IM
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pubmed:chemical |
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pubmed:status |
MEDLINE
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pubmed:month |
May
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pubmed:issn |
0009-2363
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pubmed:author |
|
|
pubmed:issnType |
Print
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pubmed:volume |
51
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pubmed:owner |
NLM
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|
pubmed:authorsComplete |
Y
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pubmed:pagination |
602-4
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pubmed:dateRevised |
2006-11-15
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pubmed:meshHeading |
|
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pubmed:year |
2003
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pubmed:articleTitle |
Dianion of sulfinylacetone as a synthetic equivalent of beta-enolate of propionic acid: a novel synthesis of carboxylic acids from alkyl halides with three-carbon elongation.
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|
pubmed:affiliation |
Department of Chemistry, Faculty of Science, Tokyo University of Science, Kagurazaka, Tokyo, Japan. tsatoh@ch.kagu.tus.ac.jp
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pubmed:publicationType |
Journal Article,
Research Support, Non-U.S. Gov't
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