12735775

Source:http://linkedlifedata.com/resource/pubmed/id/12735775

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0001128, umls-concept:C0001975, umls-concept:C0002068, umls-concept:C0020281, umls-concept:C0070570, umls-concept:C1704675, umls-concept:C1879547
pubmed:issue	10
pubmed:dateCreated	2003-5-8
pubmed:abstractText	[reaction: see text] Electrophilic activation of hydrogen peroxide can be achieved in acidic alcohol solvents without the need for a metal catalyst. This concept is illustrated by the epoxidation of alkenes with H(2)O(2) employing phenol as a solvent. It is proposed that intermolecular hydrogen bonding between H(2)O(2) and phenol activates H(2)O(2) for oxygen-atom transfer. In this interaction, the role of phenol is purely catalytic.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/100890393
pubmed:status	PubMed-not-MEDLINE
pubmed:month	May
pubmed:issn	1523-7060
pubmed:author	pubmed-author:De VosDirk EDE, pubmed-author:JacobsPierre APA, pubmed-author:WahlenJoosJ
pubmed:issnType	Print
pubmed:day	15
pubmed:volume	5
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	1777-80
pubmed:year	2003
pubmed:articleTitle	Activation of hydrogen peroxide through hydrogen-bonding interaction with acidic alcohols: epoxidation of alkenes in phenol.
pubmed:affiliation	Department of Interphase Chemistry, Centre for Surface Chemistry and Catalysis, Katholieke Universiteit Leuven, Kasteelpark Arenberg 23, B-3001 Heverlee, Belgium.
pubmed:publicationType	Journal Article