Source:http://linkedlifedata.com/resource/pubmed/id/12733882
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
19
|
| pubmed:dateCreated |
2003-5-7
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| pubmed:abstractText |
The first example of "light-driven chiral molecular scissors" (1), which consists of 1,1',3,3'-tetraarylferrocene as a pivot part and azobenzene as a driving part, was synthesized. Absorption, circular dichroism (CD), and 1H NMR spectral studies on the photoinduced isomerization process of an enantiomer of 1 agreed well with a prediction by a DFT calculation, where a motion of the handles via light-driven contraction/expansion of the connecting azobenzene strap was transformed, through a pivotal motion of the ferrocene unit, into an open-close motion of the blade parts.
|
| pubmed:language |
eng
|
| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
|
| pubmed:month |
May
|
| pubmed:issn |
0002-7863
|
| pubmed:author | |
| pubmed:issnType |
Print
|
| pubmed:day |
14
|
| pubmed:volume |
125
|
| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
|
| pubmed:pagination |
5612-3
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| pubmed:dateRevised |
2008-1-17
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| pubmed:year |
2003
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| pubmed:articleTitle |
Light-driven open-close motion of chiral molecular scissors.
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| pubmed:affiliation |
Department of Chemistry and Biotechnology, School of Engineering, The University of Tokyo,7-3-1, Hongo, Bunkyo-ku, Tokyo 113-8656, Japan.
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| pubmed:publicationType |
Journal Article
|