12659588

Source:http://linkedlifedata.com/resource/pubmed/id/12659588

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0051225, umls-concept:C0205250, umls-concept:C0220781, umls-concept:C1883254
pubmed:issue	7
pubmed:dateCreated	2003-3-27
pubmed:abstractText	[reaction: see text] The geometrical isomers of 6-ethylidenedioxadisilacyclohexane were prepared by intramolecular hydrosilylation of an unsymmetrical disiloxane by the use of Pt (syn) and Ru (anti) catalysts. This new class organosilicon reagents underwent cross-coupling reactions with a range of aryl iodides to afford (E)- and (Z)-trisubstituted allylic alcohols in a highly stereospecific fashion.
pubmed:grant	http://linkedlifedata.com/resource/pubmed/grant/GM 63167
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/100890393
pubmed:citationSubset	IM
pubmed:chemical	http://linkedlifedata.com/resource/pubmed/chemical/Alcohols, http://linkedlifedata.com/resource/pubmed/chemical/Silicon
pubmed:status	MEDLINE
pubmed:month	Apr
pubmed:issn	1523-7060
pubmed:author	pubmed-author:DenmarkScott ESE, pubmed-author:PanWeitaoW
pubmed:issnType	Print
pubmed:day	3
pubmed:volume	5
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	1119-22
pubmed:dateRevised	2007-11-14
pubmed:meshHeading	pubmed-meshheading:12659588-Alcohols, pubmed-meshheading:12659588-Molecular Structure, pubmed-meshheading:12659588-Silicon, pubmed-meshheading:12659588-Stereoisomerism
pubmed:year	2003
pubmed:articleTitle	Intramolecular syn and anti hydrosilylation and silicon-assisted cross-coupling: highly regio- and stereoselective synthesis of trisubstituted allylic alcohols.
pubmed:affiliation	Department of Chemistry, 245 Roger Adams Laboratory, 600 South Mathews Avenue, Urbana, Illinois 61801, USA.
pubmed:publicationType	Journal Article, Research Support, U.S. Gov't, P.H.S.