Source:http://linkedlifedata.com/resource/pubmed/id/12658652
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
7
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pubmed:dateCreated |
2003-3-26
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pubmed:abstractText |
From the lipopolysaccharides (LPSs) of the plant-pathogenic bacterium Burkholderia caryophylli, the complete structure of lipid A has been characterized. For the first time, a 4-amino-4-deoxy-L-arabinopyranose 1-phosphate residue was proven to be exclusively linked to the reducing end of lipid A from a wild-type LPS. The LPSs of B. caryophylli were degraded by mild acetate buffer hydrolysis at pH 4.4. The obtained lipid A was analyzed as such, and also after de-O-acylation or dephosphorylation. The structure of lipid A was identified mainly by means of matrix-assisted laser desorption/ionisation mass spectrometry, and by various 1D and 2D (1)H and (13)C NMR spectroscopic measurements.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:citationSubset |
IM
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pubmed:chemical | |
pubmed:status |
MEDLINE
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pubmed:month |
Apr
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pubmed:issn |
0947-6539
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pubmed:author | |
pubmed:issnType |
Print
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pubmed:day |
4
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pubmed:volume |
9
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
1542-8
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pubmed:dateRevised |
2009-8-4
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pubmed:meshHeading |
pubmed-meshheading:12658652-Acylation,
pubmed-meshheading:12658652-Arabinose,
pubmed-meshheading:12658652-Burkholderia,
pubmed-meshheading:12658652-Carbohydrate Conformation,
pubmed-meshheading:12658652-Glycosides,
pubmed-meshheading:12658652-Lipid A,
pubmed-meshheading:12658652-Molecular Structure,
pubmed-meshheading:12658652-Nuclear Magnetic Resonance, Biomolecular,
pubmed-meshheading:12658652-Phosphoric Acid Esters,
pubmed-meshheading:12658652-Phosphorylation,
pubmed-meshheading:12658652-Spectrometry, Mass, Matrix-Assisted Laser...
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pubmed:year |
2003
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pubmed:articleTitle |
The structure of lipid A of the lipopolysaccharide from Burkholderia caryophylli with a 4-amino-4-deoxy-L-arabinopyranose 1-phosphate residue exclusively in glycosidic linkage.
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pubmed:affiliation |
Dipartimento di Chimica Organica e Biochimica, Università degli studi di Napoli Federico II, Italy.
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pubmed:publicationType |
Journal Article
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